Zero-Shot Learning(ZSL) techniques could classify a completely unseen class, which it has never seen before during training. Thus, making it more apt for any real-life classification problem, where it is not possible to train a system with annotated data for all possible class types. This work investigates recognition of word images written in Bengali Script in a ZSL framework. The proposed approach performs Zero-Shot word recognition by coupling deep learned features procured from VGG16 architecture along with 13 basic shapes/stroke primitives commonly observed in Bengali script characters. As per the notion of ZSL framework those 13 basic shapes are termed as “Signature Attributes”. The obtained results are promising while evaluation was carried out in a Five-Fold cross-validation setup dealing with samples from 250 word classes.